Application of Diamond in New Electronic Packaging Substrate


Release time:

2023-05-17

Now the rapid development of microelectronics technology, electronic systems and equipment to large-scale integration, miniaturization, high efficiency, high reliability and other directions. The increase in the integration of electronic systems will lead to an increase in power density and an increase in the heat generated by the overall operation of electronic components and systems. Therefore, effective packaging must solve the heat dissipation problem of electronic systems. With the materials, devices and other aspects of technical issues continue to overcome, diamond has become a set of high thermal conductivity, good heat dissipation and other advantages in a substrate material, in a higher temperature environment, is the manufacture of low power consumption, high power density devices, the best semiconductor materials, its huge potential to attract more and more researchers into it. The potential of diamond will gradually be developed to meet the needs of the semiconductor industry in the future, and occupy a place in the semiconductor electronic packaging materials.

With the rapid development of modern microelectronics technology, electronic systems and equipment are developing in the direction of large-scale integration, miniaturization, high efficiency and high reliability. The increase in the integration of electronic systems will lead to an increase in power density and an increase in the heat generated by the overall operation of electronic components and systems. Therefore, effective packaging must solve the heat dissipation problem of electronic systems.

Good device heat dissipation depends on optimized heat dissipation structure design, package material selection (thermal interface material and heat dissipation substrate) and package manufacturing process. Among them, the selection of substrate material is the key link, which directly affects the cost, performance and reliability of the device. Generally speaking, the application of electronic packaging materials needs to consider two basic performance requirements. The first is high thermal conductivity to achieve rapid heat transfer and ensure that the chip can work stably under ideal temperature conditions; at the same time, the packaging material needs to have adjustable Thermal expansion coefficient, so as to maintain a match with the chip and all levels of packaging materials, and reduce the adverse effects of thermal stress. The development trajectory of electronic packaging materials is the continuous improvement and optimization of these two properties.

new typePackage substrateOf course, the material also needs to consider other properties, such as high resistivity, low dielectric constant, dielectric loss, good thermal matching with silicon and gallium arsenide, high surface flatness, good mechanical properties and easy industrial production. Therefore, the choice of new packaging substrate materials is a hot spot for research and development in various countries. At present, several commonly used packaging substrates are Al2O3 ceramics, SiC ceramics, AlN and other materials.

As early as 1929, the German Siemens company successfully developed Al2O3 ceramics, but the coefficient of thermal expansion and dielectric constant of Al2O3 relative to Si single crystal is high, the thermal conductivity is not high enough, resulting in Al2O3 ceramic substrate is not suitable for high frequency, high power, very large scale integrated circuit use.

Then the high thermal conductivity ceramic substrate material SiC, AlN, SI3N4,DiamondGradually enter the market.

The thermal conductivity of SiC ceramics is very high, and the higher the purity of SiC crystals, the higher the thermal conductivity; the biggest disadvantage of SiC is that the dielectric constant is too high and the dielectric strength is low, so it limits its high-frequency applications and is only suitable for low-density packaging.

AlN material has excellent dielectric properties and stable chemical properties, especially its thermal expansion coefficient is matched with silicon, which makes it a promising semiconductor packaging substrate material. However, the thermal conductivity is low, and with the increasing demand for heat dissipation in semiconductor packaging, AlN materials also have certain development bottlenecks.

In the end, diamond stands out. Diamond has good comprehensive thermophysical properties. Its thermal conductivity at room temperature is 700~2200W/(m · K), and its thermal expansion coefficient is 0.8 × 10-6/K. It has many excellent characteristics in semiconductor and optical fields, but a single diamond is not easy to make into packaging materials, and the cost is high.

According to the mixing rule, the diamond/metal matrix composites prepared by adding diamond particles to high thermal conductivity metal matrices such as Ag, Cu and Al are expected to become a new type of electronic packaging material with low thermal expansion coefficient and high thermal conductivity. Based on the excellent electrical conductivity and high thermal conductivity of copper, the diamond/copper composite material was developed as a substrate material for electronic packaging, and it was confirmed that the diamond/copper composite material has good platability and solderability, meets the performance requirements of low thermal expansion coefficient and high thermal conductivity of electronic packaging substrate material, and has lower density and lighter weight than Mo/Cu alloy, therefore, the diamond/copper composite material with diamond as the reinforcing phase and copper as the matrix material can be used for chip packaging, which can improve the performance of the electronic equipment system and help reduce the weight of the equipment.

With the materials, devices and other aspects of technical issues continue to overcome, diamond has become a set of high thermal conductivity, good heat dissipation and other advantages in a substrate material, in a higher temperature environment, is the manufacture of low power consumption, high power density devices, the best semiconductor materials, its huge potential to attract more and more researchers into it. The potential of diamond will gradually be developed to meet the needs of the semiconductor industry in the future and occupy a place in the semiconductor electronic packaging materials.

Focus on hot spots

The main application of diamond powder

As a kind of super hard abrasive, diamond powder has incomparably superior grinding ability, which has been paid more and more attention by the industrial developed countries. The grinding ability of diamond powder includes the grinding ability of the workpiece and its own wear resistance and crushing resistance, depending on its microhardness, particle size, strength, particle size, and thermal and chemical stability. To sum up, diamond powder used as abrasive has three aspects; (1) Used in the manufacture of resin-bonded tools, metal-bonded tools, and plating tools. (2) for industrial, scientific and medical precision or polishing of various precision components. (3) as a fine abrasive for mold processing, gem polishing processing, gem bearing processing and manufacturing. In addition to the application of diamond powder as a grinding material, another major use is used as a functional material. For example, the use of its thermal properties and electrical properties. By mixing diamond fine powder into thermosetting resin polymer, cellulose, phenolic resin or ceramic sheet, a new material having improved thermal conductivity and reduced thermal expansion can be produced. The diamond powder mixed to the metal sheet, such as sheet or stainless steel sheet can be made with high thermal conductivity, low thermal expansion and light weight of the new sheet material, in the electronics industry can be made into high-density high-energy devices for thermal control. From the form of diamond used as grinding materials, according to the relevant data published figures, the world's industrial consumption of more than 60% of diamond powder is used to make diamond plaster, diamond powder mixture and diamond powder grinding fluid.

Ultra-precision polishing of precision instruments for the use of nanodiamonds

We add nano-diamond to the medium to make nano-diamond polishing liquid, which is now mainly divided into aqueous polishing liquid and oily polishing liquid. Because the nano-diamond polishing liquid nano-diamond particles super hard super hard, with it can remove the material surface small uneven, polished material surface roughness can be reduced to nano-level, so that the material surface finish is very high. At present, nano-diamond polishing liquid can be used in semiconductor silicon wafer polishing, computer head polishing, precision ceramic processing, gem polishing, optical glass polishing and other fields. Nowadays, due to the development of computers, people's requirements for computer storage capacity continue to increase, which makes us want to manufacture larger disks. In recent years, the storage capacity of computer disks has been increasing, but with the increase of storage capacity, the problem is that the gap between the disk and the head is getting smaller and smaller, which is close to 10NM. The surface roughness, scratches and impurity particles of the head and the disk will cause damage to the computer disk. As the distance between the disk and the head has reached the nanometer level, the micron-level polishing liquid has failed to meet the polishing requirements, so only nano diamond polishing liquid can meet the requirements of this aspect. We used nano-diamond polishing liquid to polish the computer magnetic head, and found that the surface smoothness of the magnetic head was greatly improved after polishing. The measured surface roughness at this time was 0.09~0.40nm, while the surface roughness of the magnetic head was 0.45~0.80nm after polishing with ordinary polishing liquid. Compared with nano-diamond polishing liquid, the effect of nano-diamond polishing liquid is much better, thus the quality of the computer magnetic head is also improved, and we can produce more precision, A computer disk with a larger storage capacity. It is worth noting that when polishing, because the computer and other electronic products most avoid corrosion, so be sure to control the pH of the polishing liquid, the study found that the PH value of the polishing liquid is more appropriate to control between 6.5 and 8. Since the content of anions Cl-and SO2-will determine the pH of the polishing solution, the content of Cl-and SO2-should be controlled when preparing the polishing solution for computer head polishing, and the PH value should be observed at the same time.

Characteristics of Shandong Metal Powder Hydraulic Press

Shandong metal powder hydraulic press is suitable for automatic control molding of powder dry pressing. It is widely used in electronics, powder metallurgy, soft magnetic industry, conductive dry pressing molding, chemical industry, automobile manufacturing, medicine, energy and environmental protection industry, toy industry, etc. Suitable dry-pressed powders include ferrous and non-ferrous metal powders, electronic ceramic powders, ferrites, rare earth powders, cemented carbide powders, PTFE, diamond and graphite powders, and the like. The hydraulic transmission system of Shandong metal powder hydraulic press is composed of power mechanism, control mechanism, actuator, auxiliary mechanism and working medium. The power mechanism usually uses an oil pump as the power mechanism, and is generally an integrated oil pump. One or more oil pumps are selected in order to meet the speed of movement of the actuator. Low pressure gear pump; medium pressure vane pump; high pressure piston pump. The pressure processing and forming of various plastic materials, such as the extrusion, bending, drawing of stainless steel plates and steel plates, and the cold pressing of metal parts, can also be used for the pressing of powder products, grinding wheels, bakelite and resin thermosetting products.

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